12/2/2023 0 Comments Carbon periodic table key![]() The enthalpy difference between α- and α-graphite is less than 1 kJ mol -1 (0.59 ± 0.17 kJ mol -1. although the carbon-carbon distances and the interlayer spacing remains the same as in the α-form. repeat fashion but the β-form (rhombohedral) the stacking is ABCABCABC. ![]() In most graphite (α-graphite), the layers of atoms are arranged in an ABABAB. The distance between the layers of carbon atoms is 335.4 pm. Delocalization in the bonding is evident since the C-C distances are equal and shorter than normal carbon-carbon single bonds (typcally 154 pm). Most graphite is α-graphite and it possesses a layer structure in which each carbon is directly bound to three other carbon atoms at a distance of 141.5 pm. Amorphous forms of carbon such as soot and lampblack are materials consisting of very small particles of graphite. Whereas diamond and graphite are infinite lattices, fullerenes such as buckminsterfullerene, C 60, is a discrete molecular species. Other forms of carbon include the fullerenes. Diamond is a second form of carbon but is much less common. This is also the thermodynamically most stable form. The most common form of pure carbon is α-graphite. Pure carbon is available in a number of different forms (allotropes). This form of carbon is the subject of great interest in research laboratories today. More recently, another form of carbon, buckminsterfullerene, C 60, was discovered. Diamonds are also recovered from the ocean floor off the Cape of Good Hope. Natural diamonds are found in ancient volcanic "pipes" such as found in South Africa. Carbon, as microscopic diamonds, is found in some meteorites. Graphite is one of the softest known materials while diamond is one of the hardest. While silicon might take the place of carbon in forming a host of related compounds, it is not possible currently to form stable compounds with very long chains of silicon atoms.Ĭarbon is found free in nature in three allotropic forms: amorphous, graphite, and diamond. Organic chemistry, a 1/112th subset of inorganic chemistry, is the study of carbon and its compounds. Carbon is unique among the elements in the vast number of variety of compounds it can form. The atmosphere of Mars is very thin but what there is contains about 95 % CO 2.Ĭoal, petroleum, and natural gas are chiefly hydrocarbons. It is a component of rocks as carbonates of calcium (limestone), magnesium, and iron. Carbon is present as carbon dioxide in the atmosphere and dissolved in all natural waters. It is found in abundance in the sun, stars, comets, and atmospheres of most planets. Carbon is a Group 14 element and is distributed very widely in nature.
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![]() Finding the right red hair shade is key not only to make yourself flattering but also to communicate the right message to the audience and people around you. When red is on your head there is what people will perceive you about. Red hair color is not only fantastic but also an attitude. For instance, if your undertone is golden yellow, going for golden honey isn’t a good idea. This is like duplicating and there will be a color clash impact. It is always advisable to avoid any hair color shade that too close to your undertones. ![]() For blue or dark brown, darker shades contrasts to make them pop. Lighter shades work well to make green and hazel eyes stand out. The variety of eye colors suits perfectly to their contrasting colors on the color wheel. To make your eyes pop, go for a complementing shade for hair color. While deciding on your hair color also consider your eyes color. Some of the colors that will make you washed out include, red-purple hues, yellow red and probably cold red hair color. Brown shades like rich chocolate are also stunning. For your childhood richer locks, going lighter or darker is more or less the best option.įor those girls with red undertones, going for red hues is the right movement of complementing your complexion and hair color. The undertones are well accent with this color hue. Honey blonde is flattering especially if your natural hair is light, blonde or sandy brown. Conversely, if you have a cool skin tone, warm highlights are suitable to create a radiant face and shiny hair appearance.īlonde is a nice hair color for warm skin tones, you can see some beautiful styles here. This is the only way to make the golden yellow undertones sparkle. Women with warm skin tones look attractive and flattering in cool highlights. It is also going to save you from hair coloring damages. ![]() Natural hair color is the best and this rule will help you avoid looking artificial. It the rule of the thump you maintain within the three shades of your natural hair color if you are to change your appearance. If you can identify yourself with any of these celebrities then you are likely to tell your skin tone.īest Hair Colors for Warm Skin Tones best hair color for warm skin tones – red highlights On the other hand, celebrities with cool skin tones include January Jones, Scarlett Johansson, Anne Hathaway, Lucy Liu, Cameron Diaz, and Cara Delevingne. Jennifer Lopez, Nicole Kidman, Jessica Alba, Rachel Bilson, Jennifer Aniston, Beyoncé. The skin turns to golden brown when subjected to sunlight. Warm women, on the other hand, have like brown, orange, and tan colors for clothing. Your skin burns or turns to pink when exposed to sunlight. When you are cool skin you look attractive in white, black or ivory colors of wearing. This does not always hold and variations can arise. The skin undertones are golden, orange, yellow or reddish. Hair color is mostly, dark blonde, black, brown or dark. For warm skin, eyes color include brown, golden or hazel. Skin undertones include blue, pink, silver or ash. The hair color is blonde, brown, dark or black. Most cool skin individuals have blue, gray or green eyes. When you look perfect in golden jewelry, this implies that your skin tone is warm and on the other hand if silvery or platinum jewelry suits you best, this implies that cool skin tone is where you automatically fall. Conversely, if they are green it shows that you are a warm skin woman. When you look at the veins at your wrist or underarm and you notice that they have a blue tinge, this shows that you have a cool skin tone. They are simple and straightforward to follow and within no time you will be able to identify your skin tone. There are a number of ways upon which you can easily determine your skin tone. Clothing color How to Determine Your Skin Tone?.Factors to Consider when choosing the best Hair Color Poor colors for your hair can also make you look awkward since they can fade easily upon exposure to the sunlight. You can not only damage your hair but also look washed out. Selecting the right hair color for your skin tone is not an easy task. 7.3 Bluish Green hazel eyes Hair Color Ideas for Warm Skin Tones 12/2/2023 0 Comments Open td bank online![]() ![]() †By clicking on this link you are leaving our website and entering a third-party website over which we have no control. Please see our Personal Deposit Account Agreement for full details.ĤDeposits follow our Funds Availability Policy. Items are processed, and funds are made available to your Account based on our Processing Order and Funds Availability Policies. ET the next business day, we refund the overdraft fees that were assessed to your account for will refund the overdraft fees that were assessed to your account for those items.ģFor the purposes of determining your available Account balance and processing items to your Account, including deposits made in an attempt to bring the available Account balance to at least $0, all items are processed overnight at the end of each Business Day (which excludes Saturdays, Sundays, and federal holidays). For example, preauthorized transactions and other transactions may post to your Account even when the available balance in your Account is not sufficient to pay the transaction.ĢIf you overdraw your available account balance by more than $50, and you make a deposit to bring your available account balance back to at least $0 as of 11p.m. Transactions that you make may cause your Account to overdraw but we will not assess your TD Essential Banking Account an overdraft fee. We may decline or return transactions that would result in an overdraft. For more information see the Personal Deposit Account Agreement.ġOverdraft Services do not apply to TD Essential Banking Accounts. The order in which transactions are processed may affect the total amount of overdraft fees incurred. TD Debit Card Advance SM is different from other forms of overdraft coverage in that it does not transfer funds from an approved line of credit, savings account, or home equity line of credit. For example, we typically do not pay overdrafts if your account is not in good standing, you are not making regular deposits, or you repeatedly overdraft. Whether an overdraft will be paid is our discretion, and we reserve the right not to pay. You are obligated to pay overdrafts immediately. A $35 fee applies to each transaction that overdraws your available account balance by more than $50, whether that transaction is made by debit card, check, in-person withdrawal, or other electronic means (up to a maximum of 3 fees per day per account). * Important Details about TD Debit Card Advance SMīy enrolling in TD Debit Card Advance SM, you are permitting us to authorize and pay ATM and one-time debit card transactions when you do not have enough money available in your account to cover the transaction. If you have any questions or concerns about which service is right for you, talk with a representative at your local TD Bank. You can find the full definitions of these terms, and others, in 48 CFR 19. The SBA calculates number of employees in accordance with 13 CFR 121.106. The number of employees of a concern in business less than 24 months is the average for each pay period that it has been in business. Any person on the payroll must be included as one employee, regardless of hours worked or temporary status. Public companies in the S&P 500 sell for an average of 17-times earnings. Business owners earn the highest salaries in Washington (120,339), New Jersey (110,331), and New York (109,284). small and large companies as it relates to earnings. Wachtell’s profits per partner were 4.3 million. Business owners' hourly rates in the US typically range between 12 and 45 an hour. Based on the 2010 General Counsel Compensation Survey, the top 100 general counsels took home average total cash compensation of 1.56 million. The average business owner salary ranges between 27,000 and 94,000 in the US.
12/2/2023 0 Comments Adorable cute anime wolf pup![]() Under the National Stock Dog registry system, each time that a dog changed ownership, the previous owner’s name was deleted and the new owner’s name was entered as the prefix to the dog’s name. 70 Names Inspired by the Hit Australian Cartoon. Naming your dog is a tough job, and you should find the proper fit for their character and personality. Belshazzar – Hebrew name meaning “protect the king”. Foxy: One of many popular names for dogs with red or orange coats. Badass Working Dog Names Badass Military Dog Names Badass Hunting Dog Names Badass Dog Names Inspired by Greek … 400 Badass Military Dog Names. Be sure to tag your adventurous Australian shepherd with a sturdy, customizable collar or LL Bean’s outdoor-ready monogrammed … Struggling over what to name your new female puppy? Check out the most popular girl dog names based on AKC registration and enrollment data for 2022. Below are 750+ badass working-dog names for your hunting, military, and sled dog names. It would fit her identity better than something cheesy. If you’re looking for some amazing Australian Cattle Dog names, look no further. But there are people in this world who run marathons, weld things, construct aircraft carriers, and do other tough-person tasks who would like their Pomeranian, shih … Here are several options of guard dog names for you to choose from, which resemble the true nature of your puppy. ![]() Genghis Khan: founder of the Mongolian Empire. Many dog parents are searching for Badass dog names for Australian Shepherds. Need names for male, Australian Sheppard. Sudden, drastic flow of snow down a steep slope. Sirius – Animagus in Harry Potter, last name Black Strom – X-Men team member Bow – the pit bull from the movie Snatch Lagertha – fearsome Viking shieldmaiden Brandy – the loyal pit bull in Once Upon a Time in Hollywood Cloud – famous for tracking down and capturing … The magical northern lights, best seen from cold places like Iceland or Alaska, are also referred to as the aurora borealis. Badass dog names should add to making your dog tough and intimidating. We hope … What are some badass dog names? Badass Dog Names Inspired by Just Being Badass. These names are handpicked from our Rover. To help you to start the process of choosing a good name for your little dog, we’ve handpicked a comprehensive list of the best badass working dog names for male and female puppies. Here is our list of police dog names for the loyal working dog. Baxter – Anchorman: The Legend of Ron Burgundy. While the last twelve months have brought a ton of hardships, there’s no denying that 2020 was also a year for adopting, rescuing and buying dogs. If you're looking for a country dog name that evokes a down-to-earth lifestyle and love of the wide-open spaces, 150 of the Most Badass Dog Names You've Ever Heard. The fact that your dog is female doesn’t mean its name has to be all cute and cuddly. Most of Bluey's episodes focus on the Heeler family, primarily games with Bluey, Bingo, and their parents-who really, really commit to the bit. Dianna – Roman Goddess of the hunt and the moon. Floyd is the name of a solid professional boxer that has won so many fights. Here are some of our favorites to help you make your decision: Argo: Celtic name … Ansel – English name meaning “protector”. For instance, short kennel affixes are easier to Sassy Names For Dogs. Are you looking for badass dog names for your new pup? Here are our favorite cool dog names for hunting dogs, video game lovers, superhero fans, and more! Skip to content. Either way, … It’s perfect for a dog with an adventurous spirit. Dog Gear Product reviews and buying guides from our team of expert reviewers. You can get these badass dog names for Australian Shepherd for Aussie dog. There is no shortage of names to name your male hunting dog. Melania, Melanie, Leila – arabic for dark. Ferdinand – meaning ‘courageous traveler’, so fantastic for a brave German Shepherd that loves adventures. You may use these guard dog names or working dog names as it is or put a twist of your own. These dog names range from the suave Romeo and Thiago to tough-guy names like Viper and … Australian Shepherd Dog Names. Rambo – Another iconic, tough Sylvester Stallone character. Agate … You’ll find lots of unique dog names here. From country music to western movies, there's no shortage of great country inspiration when you're naming your pooch. Central shaft for a rotating wheel or gear. 12/2/2023 0 Comments Classic pac man online![]() ![]() Software description provided by the publisher. Play Emulator has the largest collection of the highest quality Pac-Man Games for many emulators online. ![]() Includes 5 titles that can be played with friends and family in local multiplayer mode! There are even games for two players to take turns, so everyone gets to enjoy PAC-MAN together!Ĭollect items every time you play, and customize your very own arcade with them! Play Pac-Man Games online for free in your browser. But as technology improved, new characters were added, such as the lovely Ms. zip format so you will need to have Winzip installed on your computer to open the file. It began as a simple maze-based arcade game. Steer Pac Man with the arrow keys, avoid the ghosts, and chomp all the pellets. PacMan and his ghost friends have evolved a lot over the past few decades. Whether you love the original PAC-MAN's side-scrolling action or the puzzle genre, this collection has something for everyone! PacMan Online for Free - Play & Read About the Classic Game, September 2023. Play all 14 legendary titles like the classic PAC-MAN and PAC-LAND, as well as the newly included PAC-IN-TIME and PAC-MAN 256. For me, that meant summer trips through Poland. The player must move through the maze with the yellow creature and eat all. Play a variety of classic and nostalgic PAC-MAN games across many genres! When I was growing up, my dad had the best job I could possibly imagine: he was an arcade game and pinball technician. Pacman Classic is an online version of the arcade classic Pac-Man. 100 customisable popular game concepts to easily create your. Pac-Man, which Namco had little involvement with. Super Pac-Man is Namcos take on a sequel to the original Pac-Man Midway had previously released Ms. It was distributed in North America by Midway Games. PAC-MAN MUSEUM+ includes 14 titles from the legendary PAC-MAN series! How do I create Pacman games online Personalise the appearance and user. From Wikipedia, the free encyclopedia: Super Pac-Man is a 1982 maze chase arcade game developed and published by Namco. The classic game Pacman, walk through a maze, eat the dots and watch out for ghosts in these quality flash remakes of. 12/2/2023 0 Comments Gawker lawsuitBollea, the man, they said, was personally harmed by the publication of the video. Bollea’s attorneys argued that not only did their client not know the tape was being recorded, but when he spoke about his sex life later on a radio show, he did so in character as Hulk Hogan. While Gawker cried First Amendment protection, Bollea’s attorney cried foul and said it was a clear invasion of privacy. So far, he has won $60 million for emotional stress and $55 million in economic damages. ![]() Bollea sued Nick Denton’s Gawker Media and the former editor of, Albert J. At issue was a one minute and 41 second video which Gawker posted that showed the famed wrestler having sex with Heather Clem, the wife of his best friend. PREVIOUS, FRIDAY PM: Hulk Hogan, whose real name is Terry Bollea, has landed a $115M judgment against online site Gawker for invasion of privacy in a case that is likely to have repercussions of how celebrity news is covered in the future. Gawker, Denton and Daulerio are expected to appeal. The total damages awarded Bollea is now $140M. Gawker’s financials also showed, among other things, that it earned $6.5M in operating income in 2014 on revenues of $44.3M. Thiel was named in doing so for Gawker’s involvement in a 2007 article, which disclosed Thiel, the co-founder of PayPal and an early Facebook investor, as gay before the Silicon Valley billionaire made his sexuality public.Gawker Suspends Operations Amid Bustle Digital Group Layoffsīerry told jurors today that the $115M amount “could be debilitating for Gawker Media.” The company released financials to the court earlier that showed Gawker Media was worth $83M, and that Denton was worth anywhere between $117M-$121M because of his interest in the company, but personally is worth an estimated $3.6M. ![]() If the plaintiff wins, it is common to share the third-party portion of the proceeds. Thiel bankrolled the case was justified as “third-party litigation funding,” which is not illegal and is quite common. The billionaire fundingįorbes Magazine later revealed that Peter Thiel, a Silicon Valley billionaire, holds the financial backing of Hogan’s lawsuits against Gawker and their owner Denton. The lawsuit is for undisclosed monetary damages. In addition to Gawker, Hogan was reportedly going after a group of Florida residents for allegedly sending at least one of the sex tape recordings to Gawker. The ruling made the company accountable for $15 million in punitive impairments, Denton for $10 million, and Daulerio for $100,000. Hogan was given an added $25 million in corrective damages following his $115 million lawsuit victory. The verdict granted him $55 million in economic injuries and $60 million for emotional distress. A Florida jury led in favor of Hogan, and he was initially awarded $115 million in the lawsuit. Terry Gene Bollea took the stand in March in his invasion of privacy lawsuit against Gawker, officially maintaining that he is no longer the character he portrayed as Hulk Hogan. ![]() He explained that he used the racist insult because he was resentful about a situation between his daughter and her boyfriend. ![]() Hogan took to ABC’s Good Morning America and asked his fans for forgiveness after his banishment from the WWE. The WWE was then provoked to terminate its contract with the Hall of Famer, completely erasing him from its history. Hogan was recorded using the n-word while mentioning his daughter Brooke’s boyfriend. In July 2015, the National Enquirer and RadarOnline leaked racist audio from a separate Hogan sex tape with Heather Clem. Soon after filing his suit against the Clems, Hogan reached a $5,000 settlement with Bubba Clem in October 2012. Gawker said it acquired the video from an anonymous source and, therefore, that it should be protected under the First Amendment. Hogan and his lawyers’ team pursued $100 million in damages from Gawker since declaring he was clueless he was being filmed. Hogan furthermore sued Gawker, its founder Nick Denton and the author of the original post, A.J. A post shared by Hulk Hogan later sued Bubba and Heather Clem for plotting to record the sex tape without him being aware. 12/1/2023 0 Comments Eggplant stacks ricottaThe giveaway ends Sunday July 27th, 2014 at midnight. I’ve made it many times for family and friends and have heard nothing but compliments, not to mention my kids love it!Īlso, in case you missed my last post, be sure to enter my Giveaway of $110 gift basket worth of gluten-free, eggless Glutino Food products! For details on how to enter, go straight to this post or click here to enter through Facebook. This version of Eggplant Parmesan is not only healthier, but is also packed full of flavor. 2 eggplants 2 tsp kosher salt cup flour 3 large eggs, beaten cup parmesan cheese, grated cup panko seasoned Italian breadcrumbs 8 slices fresh mozzarella, 3 cups Italian tomato sauce 15 oz. Pan-fried breaded eggplant slices and a cottage cheese mixture, combined with mushrooms, bell peppers, onions, spinach, spices, herbs, and marinara, all stacked and topped with mozzarella cheese, fresh herbs, and a drizzle of balsamic vinegar. In this eggplant rollatini recipe, I wrap delicate planks of roasted eggplant around a rich blend of lemon zest, pecorino, and ricotta cheese. Being someone who was never a big fan of cottage cheese, I can’t tell the difference in the dish and in fact, love the flavor. I see those pretty little purples at the farmers. For the cheese layer, I use cottage cheese instead of ricotta, which is healthier and has more protein. More Eggplant Sorry, but I have been on an eggplant kick lately. I also pan fry the slices using a little oil. I have moved from store-bought seasoned breadcrumbs (many preservatives) to my own seasoning. This recipe uses a combination of water and flour as a batter to dip the eggplant slices prior to breading them. This recipe was adapted from my mom’s recipe for Eggplant Parmesan from 20 years ago, but I’ve tweaked it and added many more components. I have been consistently making it the same way, so I figured it’s about time to share it. I finally perfected my Eggplant Parmesan recipe. I actually intended on sharing the recipe with all of you a few years ago, but never pinned the recipe down because of the tiny changes and improvements I made when I would create this dish. This dish has been in my family for more than 20 years. Sometime around college when I gave up eating eggs, I quickly realized that most restaurants use eggs in the breading batter. Not that I don’t eat fried food, but the eggs combined with deep fried breaded eggplant slices soon put an end to ordering this dish. I loved that crispy outer texture of the breaded eggplant slices. I used to order Eggplant Parmesan at restaurants growing up. There’s one Italian dish that I’ve been making for years that I have yet to share – my recipe for Eggplant Parmesan. ![]() ![]() From various pastas, pizzas, desserts, and sandwiches, we love all of it. 12/1/2023 0 Comments Video game designer jobs san diego![]() We work in a huge variety of fields from art, storytelling, game direction, audio, script, programming, and design. ![]() We are among the largest video game development organizations, with over 8,000 game makers. If you’re ready to change the game, you’ve come to the right place. ![]() We believe amazing games and experiences start with teams as diverse as the players and communities we serve. We are a global team of creators, storytellers, technologists, experience originators, innovators and so much more. Latest Games Coming Soon Free-To-Play EA SPORTS EA Originals Games Library PC PlayStation 5 Xbox Series X Nintendo Switch Mobile Pogo EA Play The EA app Competitive Gaming EA Play Live Playtesting Company EA Studios Careers Our Technology EA Partners News Inside EA Our Commitments Positive Play Inclusion & Diversity Social Impact People & Culture Environment Help Forums Player and Parental Tools Accessibility Press Investors Careers Teams Locations Early Careers Why EA Inclusion & Diversity Latest Games Coming Soon Free-To-Play EA SPORTS EA Originals Games Library PC PlayStation 5 Xbox Series X Nintendo Switch Mobile Pogo EA Play The EA app Competitive Gaming EA Play Live Playtesting Company EA Studios Careers Our Technology EA Partners News Inside EA Our Commitments Positive Play Inclusion & Diversity Social Impact People & Culture Environment Help Forums Player and Parental Tools Accessibility Press Investors Careers Teams Locations Early Careers Why EA Inclusion & Diversity Careers at Electronic Arts - Start your Job Search - Official EA Site EA Play FIFA 23 F1™ 22 Madden NFL 23 Apex Legends Battlefield™ 2042 The Sims 4 12/1/2023 0 Comments Felt cute might delete later xx![]()
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